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For this reason the level of acidity must be very carefully regulated. Ni(C0)4 reacts with LiR to form an unstable acyl nickel carbonyl complex which can be attacked by electrophiles such as H or R'Br Halogens regenerat- halide and proton donors give the corresponding to give aldehydes A 0 -co It LiR [Ni(C0)4] Li[R- C-Ni(CO)3]- solvent 0 LiR HCONMe2 LiR R'CONMe2 2LiR 3CO - LiNMe2 RCHO LiNMe2 R'COR 2LiCO R2CO 0 I LiBr R-C-R' II e the parent alkyl (or aryl) or ketones by solvent-induced reductive elimination: LiR-C-H [(solvent)Ni(CO)3] [Fe(CO)j] reacts si-milarly.
Hemorrhagic fevers are char- acterized by copious bleeding, particularly of internal organs. Triglycerides Three classes of lipids important to living things contain fatty acids: triglycerides (fats), phospholipids.
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