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: Cr 2HCl(g) CrC12 H2 reflux MC13 3HBr (excess) ------ MBr3 3HC1 - (M Ln or Pu) 3TaC15 5AlI3(excess) - - 3TaI5 5AlC13 Reductive halogenation can be achieved by reducing a higher halide with the parent metal, another metal or hydrogen: TaIs Ta thermal gradient 630" - 575" 3WBr5 A1 thermal gradient 3WBr4 AlBr3 475"- 240" 400" TII4 such as chronic obstructive pulmonary disease.

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